Vitamin E for face benefits: Vitamin E oil can be used on your face as an overnight anti-aging treatment. Since vitamin E has a thick consistency, it’s best to apply it before bed so that it can fully absorb. > Hyperpigmentation: Dark patches on your skin can be caused by too much pigment (melanin), which is triggered by hormones or other causes. Called melasma, this condition is treatable through the use of topical vitamin E. > Preventing aging and wrinkles on your face Vitamin E is high in antioxidants, and it affects blood circulation. That might be why people notice a difference in the firmness and structure of their skin after topical use of vitamin E oil.